SF4·N(C2H5)3: the first conclusively characterized SF4 adduct with an organic base
dc.contributor.author | Goettel, James T. | |
dc.contributor.author | Chaudhary, Praveen | |
dc.contributor.author | Hazendonk, Paul | |
dc.contributor.author | Mercier, Hélène P. A. | |
dc.contributor.author | Gerken, Michael | |
dc.date.accessioned | 2021-08-10T17:31:42Z | |
dc.date.available | 2021-08-10T17:31:42Z | |
dc.date.issued | 2012 | |
dc.description | Accepted author manuscript | en_US |
dc.description.abstract | Sulfur tetrafluoride and triethylamine react at low temperatures to form a 1 : 1 adduct. The unambiguous characterization of the SF4 N(C2H5)3, which is only stable at low temperature, proves the Lewis acid property of SF4 towards organic Lewis bases. The S–N bond has a length of 2.384(2) A ̊ and is an archetypical example of a dative SIV ’N bonding modality | en_US |
dc.description.peer-review | Yes | en_US |
dc.identifier.citation | Goettel, J. T., Chaudhary, P., Hazendonk, P., Mercier, H. P. A., & Gerken, M. (2012). SF4·N(C2H5)3: The first conclusively characterized SF4 adduct with an organic base. Chemical Communications, 48, 9120-9122. https://doi.org/10.1039/C2CC34578A | en_US |
dc.identifier.uri | https://hdl.handle.net/10133/5991 | |
dc.language.iso | en_US | en_US |
dc.publisher | Royal Society of Chemistry | en_US |
dc.publisher.department | Library | en_US |
dc.publisher.faculty | Arts and Science | en_US |
dc.publisher.institution | University of Lethbridge | en_US |
dc.publisher.institution | McMaster University | en_US |
dc.publisher.url | https://doi.org/10.1039/C2CC34578A | en_US |
dc.title | SF4·N(C2H5)3: the first conclusively characterized SF4 adduct with an organic base | en_US |
dc.type | Article | en_US |
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