SF4·N(C2H5)3: the first conclusively characterized SF4 adduct with an organic base
Loading...
Date
Journal Title
Journal ISSN
Volume Title
Publisher
Royal Society of Chemistry
Abstract
Sulfur tetrafluoride and triethylamine react at low temperatures
to form a 1 : 1 adduct. The unambiguous characterization of the
SF4 N(C2H5)3, which is only stable at low temperature, proves
the Lewis acid property of SF4 towards organic Lewis bases. The
S–N bond has a length of 2.384(2) A ̊ and is an archetypical
example of a dative SIV ’N bonding modality
Description
Accepted author manuscript
Keywords
Citation
Goettel, J. T., Chaudhary, P., Hazendonk, P., Mercier, H. P. A., & Gerken, M. (2012). SF4·N(C2H5)3: The first conclusively characterized SF4 adduct with an organic base. Chemical Communications, 48, 9120-9122. https://doi.org/10.1039/C2CC34578A