The monophosphaamidine functional group

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dc.contributor.authorMasuda, Jason D.
dc.contributor.authorUniversity of Lethbridge. Faculty of Arts and Science
dc.contributor.supervisorBoeré, René T.
dc.date.accessioned2007-05-12T19:23:58Z
dc.date.available2007-05-12T19:23:58Z
dc.date.issued2002
dc.degree.levelMasters
dc.descriptionxxxii, 280 leaves : ill. ; 28 cm.en
dc.description.abstractThe synthesis and characterization of two new bulky N,P-monophosphaamidines (also known as C-aminophosphaalkenes) are described. These phosphorus analogues to amidines are shown to exhibit isomerism and tautomerism in solution that is characteristic tothe amidine functional group. In addition, the nature of the P=C-N system is examined using DFT techniques. Metal complexes of the title compounds with Group 6 metal carbonyls (L-M(CO)5, M=Cr,Mo,W) are also described. A new primary phosphane is reported that contains the sterically bulky, 2,6-diisoropylphenyl (Dip) group, along with mono and disilylated derivatives. Also included is the synthesis and characterization of a new bulky N,N',P-monophosphaguanidine.en
dc.identifier.urihttps://hdl.handle.net/10133/191
dc.language.isoen_USen
dc.publisherLethbridge, Alta. : University of Lethbridge, Faculty of Arts and Science, 2002en
dc.publisher.departmentDepartment of Chemistry and Biochemistry
dc.publisher.facultyArts and Science
dc.relation.ispartofseriesThesis (University of Lethbridge. Faculty of Arts and Science)en
dc.subjectPhosphorus compoundsen
dc.subjectAmidinesen
dc.subjectDissertations, Academicen
dc.titleThe monophosphaamidine functional groupen
dc.typeThesisen
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