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dc.contributor.author Goettel, James T.
dc.contributor.author Turnbull, Douglas
dc.contributor.author Gerken, Michael
dc.date.accessioned 2021-08-09T16:58:39Z
dc.date.available 2021-08-09T16:58:39Z
dc.date.issued 2015
dc.identifier.citation Goettel, J. T., Turnbull, D., & Gerken, M. (2015). A new synthetic route to rhenium and iodine oxide fluoride anions: The reaction between oxoanions and sulfur tetrafluoride. Journal of Fluorine Chemistry, 174, 8-13. https://doi.org/10.1016/j.jfluchem.2014.07.001 en_US
dc.identifier.uri https://hdl.handle.net/10133/5990
dc.description Accepted author manuscript en_US
dc.description.abstract Sulfur tetrafluoride is a reagent for the one-step syntheses of [ReVIIO2F4]−, [IVOF4]−, and [IVIIO2F4]− salts. Pure Ag[ReO2F4] as well as its CH3CN coordination compounds were obtained from CH3CN solvent. The Ag[ReO2F4], [Ag(CH3CN)2][ReO2F4], and [Ag(CH3CN)4][ReO2F4] salts were characterized by Raman spectroscopy. The [Ag(CH3CN)4][ReO2F4]·2CH3CN coordination compound was characterized by single-crystal X-ray diffraction. The reaction of SF4 with KIO4 in anhydrous HF gave the known K[IO2F4] salt. The reaction of [N(CH3)4]IO3 with SF4 in CH3CN yielded the new [N(CH3)4][IOF4] salt, which was characterized by Raman spectroscopy. en_US
dc.language.iso en_US en_US
dc.publisher Elsevier en_US
dc.subject Rhenium oxide fluoride en_US
dc.subject Iodine oxide fluoride en_US
dc.subject.lcsh Sulfur tetrafluoride
dc.subject.lcsh Fluorides
dc.subject.lcsh X-ray crystallography
dc.subject.lcsh Raman spectroscopy
dc.title A new synthetic route to rhenium and iodine oxide fluoride anions: The reaction between oxoanions and sulfur tetrafluoride en_US
dc.type Article en_US
dc.publisher.faculty Arts and Science en_US
dc.publisher.department Department of Chemistry and Biochemistry en_US
dc.description.peer-review Yes en_US
dc.publisher.institution University of Lethbridge en_US
dc.publisher.institution Canadian Centre for Research in Advanced Fluorine Technologies en_US
dc.publisher.url https://doi.org/10.1016/j.jfluchem.2014.07.001 en_US


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