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| dc.contributor.author | Goettel, James T. | |
| dc.contributor.author | Turnbull, Douglas | |
| dc.contributor.author | Gerken, Michael | |
| dc.date.accessioned | 2021-08-09T16:58:39Z | |
| dc.date.available | 2021-08-09T16:58:39Z | |
| dc.date.issued | 2015 | |
| dc.identifier.citation | Goettel, J. T., Turnbull, D., & Gerken, M. (2015). A new synthetic route to rhenium and iodine oxide fluoride anions: The reaction between oxoanions and sulfur tetrafluoride. Journal of Fluorine Chemistry, 174, 8-13. https://doi.org/10.1016/j.jfluchem.2014.07.001 | en_US |
| dc.identifier.uri | https://hdl.handle.net/10133/5990 | |
| dc.description | Accepted author manuscript | en_US |
| dc.description.abstract | Sulfur tetrafluoride is a reagent for the one-step syntheses of [ReVIIO2F4]−, [IVOF4]−, and [IVIIO2F4]− salts. Pure Ag[ReO2F4] as well as its CH3CN coordination compounds were obtained from CH3CN solvent. The Ag[ReO2F4], [Ag(CH3CN)2][ReO2F4], and [Ag(CH3CN)4][ReO2F4] salts were characterized by Raman spectroscopy. The [Ag(CH3CN)4][ReO2F4]·2CH3CN coordination compound was characterized by single-crystal X-ray diffraction. The reaction of SF4 with KIO4 in anhydrous HF gave the known K[IO2F4] salt. The reaction of [N(CH3)4]IO3 with SF4 in CH3CN yielded the new [N(CH3)4][IOF4] salt, which was characterized by Raman spectroscopy. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | Elsevier | en_US |
| dc.subject | Rhenium oxide fluoride | en_US |
| dc.subject | Iodine oxide fluoride | en_US |
| dc.subject.lcsh | Sulfur tetrafluoride | |
| dc.subject.lcsh | Fluorides | |
| dc.subject.lcsh | X-ray crystallography | |
| dc.subject.lcsh | Raman spectroscopy | |
| dc.title | A new synthetic route to rhenium and iodine oxide fluoride anions: The reaction between oxoanions and sulfur tetrafluoride | en_US |
| dc.type | Article | en_US |
| dc.publisher.faculty | Arts and Science | en_US |
| dc.publisher.department | Department of Chemistry and Biochemistry | en_US |
| dc.description.peer-review | Yes | en_US |
| dc.publisher.institution | University of Lethbridge | en_US |
| dc.publisher.institution | Canadian Centre for Research in Advanced Fluorine Technologies | en_US |
| dc.publisher.url | https://doi.org/10.1016/j.jfluchem.2014.07.001 | en_US |
