A new synthetic route to rhenium and iodine oxide fluoride anions: The reaction between oxoanions and sulfur tetrafluoride

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dc.contributor.authorGoettel, James T.
dc.contributor.authorTurnbull, Douglas
dc.contributor.authorGerken, Michael
dc.date.accessioned2021-08-09T16:58:39Z
dc.date.available2021-08-09T16:58:39Z
dc.date.issued2015
dc.descriptionAccepted author manuscripten_US
dc.description.abstractSulfur tetrafluoride is a reagent for the one-step syntheses of [ReVIIO2F4]โˆ’, [IVOF4]โˆ’, and [IVIIO2F4]โˆ’ salts. Pure Ag[ReO2F4] as well as its CH3CN coordination compounds were obtained from CH3CN solvent. The Ag[ReO2F4], [Ag(CH3CN)2][ReO2F4], and [Ag(CH3CN)4][ReO2F4] salts were characterized by Raman spectroscopy. The [Ag(CH3CN)4][ReO2F4]ยท2CH3CN coordination compound was characterized by single-crystal X-ray diffraction. The reaction of SF4 with KIO4 in anhydrous HF gave the known K[IO2F4] salt. The reaction of [N(CH3)4]IO3 with SF4 in CH3CN yielded the new [N(CH3)4][IOF4] salt, which was characterized by Raman spectroscopy.en_US
dc.description.peer-reviewYesen_US
dc.identifier.citationGoettel, J. T., Turnbull, D., & Gerken, M. (2015). A new synthetic route to rhenium and iodine oxide fluoride anions: The reaction between oxoanions and sulfur tetrafluoride. Journal of Fluorine Chemistry, 174, 8-13. https://doi.org/10.1016/j.jfluchem.2014.07.001en_US
dc.identifier.urihttps://hdl.handle.net/10133/5990
dc.language.isoen_USen_US
dc.publisherElsevieren_US
dc.publisher.departmentDepartment of Chemistry and Biochemistryen_US
dc.publisher.facultyArts and Scienceen_US
dc.publisher.institutionUniversity of Lethbridgeen_US
dc.publisher.institutionCanadian Centre for Research in Advanced Fluorine Technologiesen_US
dc.publisher.urlhttps://doi.org/10.1016/j.jfluchem.2014.07.001en_US
dc.subjectRhenium oxide fluorideen_US
dc.subjectIodine oxide fluorideen_US
dc.subject.lcshSulfur tetrafluoride
dc.subject.lcshFluorides
dc.subject.lcshX-ray crystallography
dc.subject.lcshRaman spectroscopy
dc.titleA new synthetic route to rhenium and iodine oxide fluoride anions: The reaction between oxoanions and sulfur tetrafluorideen_US
dc.typeArticleen_US
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