Show simple item record Begum, Imtiaz Schnakenburg, Gregor Kelemen, Zsolt Nyulászi, Laszlo Boeré, René T. Streubel, Rainer 2019-05-12T21:30:30Z 2019-05-12T21:30:30Z 2018
dc.identifier.citation Begum, I., Schnakenburg, G., Kelemen, Z., Nyulászi, Boeré, R. T., & Streubel, R. (2018). Expanding the chemistry of ring-fused 1,4diphosphinines by stable mono anion formation. Chemical Communications, 54, 13555-13558. DOI: 10.1039/c8cc08158a en_US
dc.description Sherpa Romeo yellow journal. Permission to archive author version en_US
dc.description.abstract A new sulfur-enriched tricyclic 1,4-diphosphinine (2) was synthesized and novel reactivity studies on the phosphorus heterocycle was performed: A weak anionic nucleophile (KHMDS) adds selectively thus forming a stable anionic 1,4-diphosphinine derivative (3b) which was fully characterized. The substitution potential of 3b was demonstrated using Ph2PCl to give 4b, while oxidation of 3b using elemental iodine furnished cleanly the P-P coupling product 5. en_US
dc.language.iso en_US en_US
dc.publisher Royal Society of Chemistry en_US
dc.title Expanding the chemistry of 1,4diphosphinines by stable mono anion formation en_US
dc.type Article en_US
dc.publisher.faculty Arts and Science en_US
dc.publisher.department Department of Chemistry and Biochemistry en_US
dc.description.peer-review Yes en_US
dc.publisher.institution Institut für Anorganische Chemie der Rheinischen Friedrich-Wilhelms-Universität Bonn en_US
dc.publisher.institution Budapest University of Technology and Economics en_US
dc.publisher.institution MTA-BME Computation Driven Chemistry Research en_US
dc.publisher.institution University of Lethbridge en_US

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