Expanding the chemistry of 1,4diphosphinines by stable mono anion formation

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dc.contributor.authorBegum, Imtiaz
dc.contributor.authorSchnakenburg, Gregor
dc.contributor.authorKelemen, Zsolt
dc.contributor.authorNyulászi, Laszlo
dc.contributor.authorBoeré, René T.
dc.contributor.authorStreubel, Rainer
dc.date.accessioned2019-05-12T21:30:30Z
dc.date.available2019-05-12T21:30:30Z
dc.date.issued2018
dc.descriptionAccepted author manuscripten_US
dc.description.abstractA new sulfur-enriched tricyclic 1,4-diphosphinine (2) was synthesized and novel reactivity studies on the phosphorus heterocycle was performed: A weak anionic nucleophile (KHMDS) adds selectively thus forming a stable anionic 1,4-diphosphinine derivative (3b) which was fully characterized. The substitution potential of 3b was demonstrated using Ph2PCl to give 4b, while oxidation of 3b using elemental iodine furnished cleanly the P-P coupling product 5.en_US
dc.description.peer-reviewYesen_US
dc.identifier.citationBegum, I., Schnakenburg, G., Kelemen, Z., Nyulászi, Boeré, R. T., & Streubel, R. (2018). Expanding the chemistry of ring-fused 1,4diphosphinines by stable mono anion formation. Chemical Communications, 54, 13555-13558. DOI: 10.1039/c8cc08158aen_US
dc.identifier.urihttps://hdl.handle.net/10133/5354
dc.language.isoen_USen_US
dc.publisherRoyal Society of Chemistryen_US
dc.publisher.departmentDepartment of Chemistry and Biochemistryen_US
dc.publisher.facultyArts and Scienceen_US
dc.publisher.institutionInstitut für Anorganische Chemie der Rheinischen Friedrich-Wilhelms-Universität Bonnen_US
dc.publisher.institutionBudapest University of Technology and Economicsen_US
dc.publisher.institutionMTA-BME Computation Driven Chemistry Researchen_US
dc.publisher.institutionUniversity of Lethbridgeen_US
dc.publisher.urlhttps://doi.org/10.1039/C8CC08158A
dc.titleExpanding the chemistry of 1,4diphosphinines by stable mono anion formationen_US
dc.typeArticleen_US
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