The monophosphaamidine functional group
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Date
2002
Authors
Masuda, Jason D.
University of Lethbridge. Faculty of Arts and Science
Journal Title
Journal ISSN
Volume Title
Publisher
Lethbridge, Alta. : University of Lethbridge, Faculty of Arts and Science, 2002
Abstract
The synthesis and characterization of two new bulky N,P-monophosphaamidines (also known as C-aminophosphaalkenes) are described. These phosphorus analogues to amidines are shown to exhibit isomerism and tautomerism in solution that is characteristic tothe amidine functional group. In addition, the nature of the P=C-N system is examined using DFT techniques. Metal complexes of the title compounds with Group 6 metal carbonyls (L-M(CO)5, M=Cr,Mo,W) are also described. A new primary phosphane is reported that contains the sterically bulky, 2,6-diisoropylphenyl (Dip) group, along with mono and disilylated derivatives. Also included is the synthesis and characterization of a new bulky N,N',P-monophosphaguanidine.
Description
xxxii, 280 leaves : ill. ; 28 cm.
Keywords
Phosphorus compounds , Amidines , Dissertations, Academic