Short contacts of the sulphur atoms of a 1,2,3,5-dithiadiazolyl dimer with triphenylstibine: first cocrystal with an aromatic compound

Simple item page
dc.contributor.authorBoeré, René T.
dc.date.accessioned2019-04-29T20:45:35Z
dc.date.available2019-04-29T20:45:35Z
dc.date.issued2016
dc.descriptionSherpa Romeo yellow journal. Gold open access article. Creative Commons Attribution 3.0 Unported License (CC BY 3.0) appliesen_US
dc.description.abstractThe structure of dimeric 2,7-bisij4-(trifluoromethyl)phenyl]-4λ4,5λ4,9λ4,10λ4-tetrathietoij1,2-a:3,4-a′]bis [1,2,3,5]dithiadiazole (C8H4F3N2S2)2 and its adduct with triphenylstibin (C8H4F3N2S2)2·C18H15Sb, both have triclinic (P¯1) symmetry. They crystallize in layers containing centrosymmetric clusters consisting of four dithiadiazolyl dimers in the parent compound and two such dimers paired with two triphenylstibine units in the aromatic co-crystal. In the co-crystal, the Ph3Sb molecules associate with an equivalent moiety from a neighbouring cluster in a geometry that is very reminiscent of other Ph3Sb-containing structures. Thus, the adduct combines structural elements from those of its component parts. Key interactions between molecules in the pure dithiadiazolyl (S to S) and the co-crystal (S to C) are significantly shorter than the sums of atom van der Waals radii.en_US
dc.description.peer-reviewYesen_US
dc.identifier.citationBoeré, R. T. (2016). Short contacts of the sulphur atoms of a 1,2,3,5-dithiadiazolyl dimer with triphenylstibine: First cocrystal with an aromatic compound. CrystEngComm, 18, 2748-2756. doi:10.1039/c6ce00351fen_US
dc.identifier.urihttps://hdl.handle.net/10133/5345
dc.language.isoen_USen_US
dc.publisherRoyal Society of Chemistryen_US
dc.publisher.departmentDepartment of Chemistry and Biochemistryen_US
dc.publisher.facultyArts and Scienceen_US
dc.publisher.institutionUniversity of Lethbridgeen_US
dc.publisher.urlhttps://dx.doi.org/10.1039/c6ce00351f
dc.subjectSulphur atoms
dc.subject1,2,3,5-dithiadiazolyl dimer
dc.subjectTriphenylstibine
dc.subjectCo-crystal
dc.subjectAdduct
dc.subject.lcshCrystallography
dc.titleShort contacts of the sulphur atoms of a 1,2,3,5-dithiadiazolyl dimer with triphenylstibine: first cocrystal with an aromatic compounden_US
dc.typeArticleen_US
Files
Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
Boeré-short-contacts-of.pdf
Size:
4.31 MB
Format:
Adobe Portable Document Format
Description:
Download
License bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
license.txt
Size:
1.75 KB
Format:
Item-specific license agreed upon to submission
Description:
Download
Collections
Boere, Rene