Synthesis and characterizations of fluorophosphoryl diazide and diisocyanate

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dc.contributor.authorSong, Chao
dc.contributor.authorChu, Xianxu
dc.contributor.authorZhu, Bifeng
dc.contributor.authorGerken, Michael
dc.contributor.authorZeng, Xiaoqing
dc.date.accessioned2021-07-22T18:28:04Z
dc.date.available2021-07-22T18:28:04Z
dc.date.issued2021
dc.descriptionAccepted author manuscript.en_US
dc.description.abstractTwo fluorine-substituted phosphoryl pseudohalides including the highly explosive diazide FP(O)(N3)2 and dii-socyanate FP(O)(NCO)2 have been synthesized and fully characterized with IR (gas-phase and noble-gas matrices), Raman (liquid), and NMR (19F and 31P) spectroscopy. The vibrational spectra of FP(O)(N3)2 and FP (O)(NCO)2 were analyzed with the aid of the B3LYP/6en_US
dc.description.peer-reviewYesen_US
dc.identifier.citationSong, C., Chu, X., Zhu, B., Gerken, M., & Zeng, X. (2021). Synthesis and characterizations of fluorophosphoryl diazide and diisocyanate. Journal of Fluorine Chemistry, 242, Article 109694. https://doi.org/10.1016/j.jfluchem.2020.109694en_US
dc.identifier.urihttps://hdl.handle.net/10133/5964
dc.language.isoen_USen_US
dc.publisherElsevieren_US
dc.publisher.departmentDepartment of Chemistry and Biochemistryen_US
dc.publisher.facultyArts and Scienceen_US
dc.publisher.institutionSoochow Universityen_US
dc.publisher.institutionFudan Universityen_US
dc.publisher.institutionUniversity of Lethbridgeen_US
dc.publisher.urlhttps://doi.org/10.1016/j.jfluchem.2020.109694en_US
dc.subjectPhosphoryl fluoridesen_US
dc.subjectConformationen_US
dc.subjectVibrational spectroscopyen_US
dc.subject.lcshAzides
dc.subject.lcshIsocyanates
dc.subject.lcshConformational analysis
dc.titleSynthesis and characterizations of fluorophosphoryl diazide and diisocyanateen_US
dc.typeArticleen_US
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