Synthesis and characterizations of fluorophosphoryl diazide and diisocyanate
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Date
2021
Authors
Song, Chao
Chu, Xianxu
Zhu, Bifeng
Gerken, Michael
Zeng, Xiaoqing
Journal Title
Journal ISSN
Volume Title
Publisher
Elsevier
Abstract
Two fluorine-substituted phosphoryl pseudohalides including the highly explosive diazide FP(O)(N3)2 and dii-socyanate FP(O)(NCO)2 have been synthesized and fully characterized with IR (gas-phase and noble-gas matrices), Raman (liquid), and NMR (19F and 31P) spectroscopy. The vibrational spectra of FP(O)(N3)2 and FP (O)(NCO)2 were analyzed with the aid of the B3LYP/6
Description
Accepted author manuscript.
Keywords
Phosphoryl fluorides , Conformation , Vibrational spectroscopy
Citation
Song, C., Chu, X., Zhu, B., Gerken, M., & Zeng, X. (2021). Synthesis and characterizations of fluorophosphoryl diazide and diisocyanate. Journal of Fluorine Chemistry, 242, Article 109694. https://doi.org/10.1016/j.jfluchem.2020.109694