Lithium complexes of ketoimines and novel alkynyl imines and diimines : discoveries in the attempted synthesis of PACNAC

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dc.contributor.authorGietz, Twyla M.
dc.contributor.authorUniversity of Lethbridge. Faculty of Arts and Science
dc.contributor.supervisorBoeré, René T.
dc.date.accessioned2011-07-18T21:13:13Z
dc.date.available2011-07-18T21:13:13Z
dc.date.issued2010
dc.degree.levelMasters
dc.descriptionxvi, 134 leaves : ill. (some col.) ; 29 cm + 1 CD-ROMen_US
dc.description.abstractTwo different methodologies were used to attempt the synthesis of a novel P‐N ligand, denoted as PACNAC for the similarity to the analogous NACNAC and ACAC ligands. Although the synthesis of PACNAC was not successful, each methodology led to interesting discoveries. First, a number of lithium complexes of ketoimines were isolated and studied by Xray crystallography and NMR spectroscopy revealing some interesting substituent based effects on the structure, solubility and solution state behaviour. The X‐ray data of the two known and two related novel ketoimines were also collected and compared to the lithium complexes. Secondly, the synthesis of novel alkynyl imines along with the new alkynyl diimines by novel synthetic routes and studied by x‐ray crystallography, NMR, electrochemistry, and UV‐Visible spectra.en_US
dc.identifier.urihttps://hdl.handle.net/10133/2481
dc.language.isoen_USen_US
dc.publisherLethbridge, Alta. : University of Lethbridge, Dept. of Chemistry and Biochemistry, c2010en_US
dc.publisher.departmentDepartment of Chemistry and Biochemistryen_US
dc.publisher.facultyArts and Scienceen_US
dc.relation.ispartofseriesThesis (University of Lethbridge. Faculty of Arts and Science)en_US
dc.subjectLigandsen_US
dc.subjectIminesen_US
dc.subjectCoordination compoundsen_US
dc.subjectOrganic compounds -- Synthesisen_US
dc.subjectLithium compoundsen_US
dc.subjectSpectrum analysisen_US
dc.subjectDissertations, Academicen_US
dc.titleLithium complexes of ketoimines and novel alkynyl imines and diimines : discoveries in the attempted synthesis of PACNACen_US
dc.typeThesisen_US
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