Synthesis and reactivity of Rh and Ir imino and azidophosphonamido complexes

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dc.contributor.authorCruz-Milette, Daisy E.
dc.contributor.authorUniversity of Lethbridge. Faculty of Arts and Science
dc.contributor.supervisorHayes, Paul G.
dc.date.accessioned2023-01-17T22:22:39Z
dc.date.available2023-01-17T22:22:39Z
dc.date.issued2022
dc.degree.levelMastersen_US
dc.description.abstractThis work reports a family of iminophosphonamido Rh and Ir cyclooctadiene (COD) complexes, [Ph2P(NR)2]M(COD), where the substituents on nitrogen vary, R = 2,4,6-trimethylphenyl (Mes) or adamantyl (Ad). The reaction chemistry of the iminophosphonamido Rh and Ir COD complexes was probed. This work also demonstrates the synthetic route to and of a family of azidophosphonamide Rh and Ir phosphazide containing ligand cyclooctadiene (COD) complexes, [Ph2P(N3R)(NR])M(COD). The unusual ligand linkage isomerism of said species is discussed. Preliminary results pertaining to bis(cyclooctene) (COE) complexes bearing both ligand types are also reported.en_US
dc.identifier.urihttps://hdl.handle.net/10133/6408
dc.language.isoen_CAen_US
dc.proquest.subject0488en_US
dc.proquest.subject0485en_US
dc.proquest.subject0490en_US
dc.proquestyesYesen_US
dc.publisherLethbridge, Alta. : University of Lethbridge, Dept. of Chemistry and Biochemistryen_US
dc.publisher.departmentDepartment of Chemistry & Biochemistryen_US
dc.publisher.facultyArts and Scienceen_US
dc.relation.ispartofseriesThesis (University of Lethbridge. Faculty of Arts and Science)en_US
dc.subjectLigandsen_US
dc.subjectCoordination chemistryen_US
dc.subjectIminophosphonamideen_US
dc.subjectAzidophosphonamideen_US
dc.subject.lcshLigands (Biochemistry)
dc.subject.lcshOrganometallic chemistry
dc.subject.lcshChemistry, Organic
dc.subject.lcshDissertations, Academic
dc.titleSynthesis and reactivity of Rh and Ir imino and azidophosphonamido complexesen_US
dc.typeThesisen_US
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