Reversible redox chemistry of anionic imidazole-2-thione-fused 1,4-dihydro-1,4-diphosphinines

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dc.contributor.authorRamachandran, Mridhul R. K.
dc.contributor.authorSchnakenburg, Gregor
dc.contributor.authorMajumdar, Moumita
dc.contributor.authorKelemen, Zsolt
dc.contributor.authorGal, Dalma
dc.contributor.authorNyulaszi, Laszlo
dc.contributor.authorBoeré, René T.
dc.contributor.authorStreubel, Rainer K.
dc.date.accessioned2022-08-16T20:25:00Z
dc.date.available2022-08-16T20:25:00Z
dc.date.issued2022
dc.descriptionOpen access article. Creative Commons Attribution 4.0 International License (CC BY 4.0) appliesen_US
dc.description.abstractAnionic 1,4-dihydro-1,4-diphosphinines were synthesized from tricyclic 1,4-diphosphinines and isolated as blue powdery salts M[2a–2c]. Reaction of solutions of these monoanions with iodomethane led to P-methylated compounds 3a–3c. An oxidation/reduction cycle was examined, starting from solutions of K[2a] via P–P coupled product 4a and back to K[2a], and the recyclability and redox chemistry of this cycle were confirmed by experimental and simulated cyclic voltammetry analysis, which is proposed as a potential 2-electron cathode for rechargeable cells. TD-DFT studies were used to examine species that might be involved in the process.en_US
dc.description.peer-reviewYesen_US
dc.identifier.citationRamachandran, M. R. K., Schnakenburg, G., Majumdar, M., Kelemen, Z., Gal, D., Nyulaszi, L., Boeré, R. T., & Streubel, R. K. (2022). Reversible redox chemistry of anionic imadazole-2-thione-fused 1,4-dihydro-1,4-diphosphinines. Inorganic Chemistry, 61(11), 4639-4646. https://doi.org/10.1021/acs.inorgchem.1c03620en_US
dc.identifier.urihttps://hdl.handle.net/10133/6318
dc.language.isoen_USen_US
dc.publisherACS Publicationsen_US
dc.publisher.departmentDepartment of Chemistry and Biochemistryen_US
dc.publisher.facultyArts and Scienceen_US
dc.publisher.institutionRheinische Friedrich-Wilhelms-Universitat Bonnen_US
dc.publisher.institutionIndian Institute of Science Education and Researchen_US
dc.publisher.institutionBudapest University of Technology and Economicsen_US
dc.publisher.institutionUniversity of Lethbridgeen_US
dc.publisher.urlhttps://doi.org/10.1021/acs.inorgchem.1c03620en_US
dc.subjectRedox reactionsen_US
dc.subject.lcshColor
dc.subject.lcshElectrodes
dc.subject.lcshEthers
dc.subject.lcshMolecular structure
dc.subject.lcshOxidation-reduction reaction
dc.titleReversible redox chemistry of anionic imidazole-2-thione-fused 1,4-dihydro-1,4-diphosphininesen_US
dc.typeArticleen_US
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