Janus bis(NHCs) tuned by heteroatom-bridge oxidation states
Date
2020
Authors
Naz, Nabila R.
Schnakenburg, Gregor
Mikehazi, Antal
Kelemen, Zsolt
Nyulaszi, Laszlo
Boeré, René T.
Streubel, Rainer
Journal Title
Journal ISSN
Volume Title
Publisher
Royal Society of Chemistry
Abstract
Synthesis of the first tricyclic bis(carbenes) with facially opposed imidazole-2-ylidenes and two linking phosphorus centres in different oxidation states is presented using a modular, high-yield synthetic route. The formation of homo bimetallic coinage metal complexes provides a glimpse on their potential use.
Description
Open access article. Creative Commons Attribution 3.0 Unported License (CC BY 3.0) applies
Keywords
Heteroatom-bridge , N-Heterocyclic carbenes , NHCs , Tricyclic bis(carbenes) , Oxidation states , Janus bis(NHCs)
Citation
Naz, N. R., Schnakenburg, G., Mikehazi, A., Kelemen, Z., Nyulaszi, L., Boere, R. T., & Streubel, R. (2020). Janus bis(NHCs) tuned by heteroatom-bridge oxidation states. Chemical Communications, 57(17), 2646-2649. https://doi.org/10.1039/C9CC08468A