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dc.contributor.author Boeré, René T.
dc.contributor.author Masuda, Jason D.
dc.contributor.author Tran, Peter
dc.date.accessioned 2019-03-31T22:48:21Z
dc.date.available 2019-03-31T22:48:21Z
dc.date.issued 2006
dc.identifier.citation Boeré, R. T., Masuda, J. D., & Tran, P. (2006). Synthesis, crystal structure and DFT calculations on 2,6-diisopropylphenylcopper: Its use in the preparation of dichloro-2,6-Diisopropylphenylphosphine. Journal of Organometallic Chemistry, 691(26), 5585-559. doi:10.1016/j.jorganchem.2006.09.004 en_US
dc.identifier.uri https://hdl.handle.net/10133/5306
dc.description Sherpa Romeo green journal. Permission to archive accepted author manuscript. en_US
dc.description.abstract The homoleptic aryl copper reagent [Cu4Dipp4] (Dipp = 2,6-diisopropylphenyl) has been prepared and structurally characterized by a single-crystal X-ray diffraction study. Its tetrameric structure differs in significant details from that of the previously reported [Cu4Tripp4] (Tripp = 2,4,6-triisopropylphenyl). The electronic structure of the cluster has been probed through B3LYP/6-3111G(2d,p)//B3LYP/6-31G calculations on [Cu4Ph4] constrained to D2d symmetry. The utility of the new copper reagent is demonstrated by the preparation of pure DippPCl2, for which the crystal structure is also reported. en_US
dc.language.iso en_US en_US
dc.publisher Elsevier en_US
dc.subject Organcopper en_US
dc.subject Dichlorophosphine en_US
dc.subject X-ray Crystallography en_US
dc.subject NMR en_US
dc.title Synthesis, crystal structure and DFT calculations on 2,6-diisopropylphenylcopper: its use in the preparation of dichloro-2,6-diisopropylphenylphosphine en_US
dc.type Article en_US
dc.publisher.faculty Arts and Science en_US
dc.publisher.department Department of Chemistry and Biochemistry en_US
dc.description.peer-review Yes en_US
dc.publisher.institution University of Lethbridge en_US
dc.publisher.url https://doi.org/10.1016/j.jorganchem.2006.09.004


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