Crystal structure of an ordered [WOF5]¯ salt: (1,10-phenH) [WOF5] (1,10-phen = 1, 10-phenanthroline
| dc.contributor.author | Turnbull, Douglas | |
| dc.contributor.author | Gerken, Michael | |
| dc.date.accessioned | 2021-07-02T16:42:13Z | |
| dc.date.available | 2021-07-02T16:42:13Z | |
| dc.date.issued | 2020 | |
| dc.description | Open access article. Creative Commons Attribution LIcense (CC BY) applies | en_US |
| dc.description.abstract | Crystals of 1,10-phenanthrolinium pentafluoridooxidotungstate(VI), (1,10-phen-H)[WOF5] (1,10-phen = 1,10-phenanthroline, C12H8N2), were obtained upon hydrolysis of WF6(1,10-phen) in CH3CN at 193 K. The (1,10-phen-H)[WOF5] salt contains a rare example of a [WOF5]− anion in which the oxygen and fluorine atoms are ordered. This ordering was verified by bond-valence determinations and structural comparisons with [Xe2F11][WOF5] and Lewis acid-base adducts of WOF4 with main-group donor ligands. The crystal packing is controlled by N—H⋯F hydrogen bonding that is directed exclusively to the axial F atom as a result of its increased basicity caused by the trans influence of the oxido ligand. | en_US |
| dc.description.peer-review | Yes | en_US |
| dc.identifier.citation | Turnbull, D., & Gerken, M. (2020). Crystal structure of an ordered [WOF5] ¯ salt: (1,10-phen-H)[WOF5] (1,10-phen = 1,10-phenanthroline. Acta Crystallographica Section E, 76(8), 1345-1348. https://doi.org/10.1107/S2056989020009767 | en_US |
| dc.identifier.uri | https://hdl.handle.net/10133/5936 | |
| dc.language.iso | en_US | en_US |
| dc.publisher.department | Department of Chemistry and Biochemistry | en_US |
| dc.publisher.faculty | Arts and Science | en_US |
| dc.publisher.institution | University of Lethbridge | en_US |
| dc.publisher.url | https://doi.org/10.1107/S2056989020009767 | en_US |
| dc.subject | Tungsten | en_US |
| dc.subject | Fluoride | en_US |
| dc.subject | Oxide | en_US |
| dc.subject | Crystal structure | en_US |
| dc.subject | O/F ordered anion | en_US |
| dc.title | Crystal structure of an ordered [WOF5]¯ salt: (1,10-phenH) [WOF5] (1,10-phen = 1, 10-phenanthroline | en_US |
| dc.type | Article | en_US |