Crystal structure of an ordered [WOF5]¯ salt: (1,10-phenH) [WOF5] (1,10-phen = 1, 10-phenanthroline

dc.contributor.authorTurnbull, Douglas
dc.contributor.authorGerken, MIchael
dc.date.accessioned2021-07-02T16:42:13Z
dc.date.available2021-07-02T16:42:13Z
dc.date.issued2020
dc.descriptionOpen access article. Creative Commons Attribution LIcense (CC BY) appliesen_US
dc.description.abstractCrystals of 1,10-phenanthrolinium penta­fluorido­oxidotungstate(VI), (1,10-phen-H)[WOF5] (1,10-phen = 1,10-phenanthroline, C12H8N2), were obtained upon hydrolysis of WF6(1,10-phen) in CH3CN at 193 K. The (1,10-phen-H)[WOF5] salt contains a rare example of a [WOF5]− anion in which the oxygen and fluorine atoms are ordered. This ordering was verified by bond-valence determinations and structural comparisons with [Xe2F11][WOF5] and Lewis acid-base adducts of WOF4 with main-group donor ligands. The crystal packing is controlled by N—H⋯F hydrogen bonding that is directed exclusively to the axial F atom as a result of its increased basicity caused by the trans influence of the oxido ligand.en_US
dc.description.peer-reviewYesen_US
dc.identifier.citationTurnbull, D., & Gerken, M. (2020). Crystal structure of an ordered [WOF5] ¯ salt: (1,10-phen-H)[WOF5] (1,10-phen = 1,10-phenanthroline. Acta Crystallographica Section E, 76(8), 1345-1348. https://doi.org/10.1107/S2056989020009767en_US
dc.identifier.urihttps://hdl.handle.net/10133/5936
dc.language.isoen_USen_US
dc.publisher.departmentDepartment of Chemistry and Biochemistryen_US
dc.publisher.facultyArts and Scienceen_US
dc.publisher.institutionUniversity of Lethbridgeen_US
dc.publisher.urlhttps://doi.org/10.1107/S2056989020009767en_US
dc.subjectTungstenen_US
dc.subjectFluorideen_US
dc.subjectOxideen_US
dc.subjectCrystal structureen_US
dc.subjectO/F ordered anionen_US
dc.titleCrystal structure of an ordered [WOF5]¯ salt: (1,10-phenH) [WOF5] (1,10-phen = 1, 10-phenanthrolineen_US
dc.typeArticleen_US
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