(2R,3aR,4S,7R,7aS,9R,10aR,11S,14R,14aS)-rel-3a,4,7,7a,10a,11,14,14aOctahydro-4,14:7,11-diepoxy-2,9propanonaphtho[1,2-f:5,6-f000]diisoindole1,3,8,10-tetrone (9CI): a cyclophane derived from naphtho[1,2-c:5,6-c]difuran
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Date
2008
Authors
Thibault, Michelle E.
Parvez, Masood
Dibble, Peter W.
Journal Title
Journal ISSN
Volume Title
Publisher
International Union of Crystallography
Abstract
The title compound, C25H18N2O6, is a naphthalenophane styled in the manner of Warrener's alicyclic cyclophanes or molecular racks wherein a trimethylene tether is perfectly staggered between the two N atoms such that the central methylene H atoms point toward the naphthalene [pi]-system. The dihedral angle between the mean planes of the two benzene rings is 7.61 (7)°.
Description
Sherpa Romeo green journal. Open access article. Creative Commons Attribution License (CC BY) applies.
Keywords
Naphthalenophane , Molecular racks , Trimethylene , Methylene , Dihedral
Citation
Thibault, M. E., Parvez, M., & Dibble, P. W. (2008). (2R,3aR,4S,7R,7aS,9R,10aR,11S,14R,14aS)-rel-3a,4,7,7a,10a,11,14,14aOctahydro-4,14:7,11-diepoxy-2,9propanonaphtho[1,2-f:5,6-f000]diisoindole1,3,8,10-tetrone (9CI): a cyclophane derived from naphtho[1,2-c:5,6-c]difuran. Acta Crystallographica Section E, Structure Reports Online, E64, o1837.