Preparation and x-ray structure of 4-N,N'-bis(trimethylsilyl)- amino-3,5-diisopropylphenylselenium trichloride

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dc.contributor.authorMaaninen, Arto
dc.contributor.authorBoeré, René T.
dc.contributor.authorChivers, Tristram
dc.contributor.authorParvez, Masood
dc.date.accessioned2019-04-29T22:26:06Z
dc.date.available2019-04-29T22:26:06Z
dc.date.issued1999
dc.descriptionOpen access article. Creative Commons Attribution 4.0 International License (CC BY 4.0) applies.en_US
dc.description.abstractThe reaction of SeCU or SeCF with /V,/V’-bis(trimethylsilyl)-2,6-diisopropylaniline occurs not at the nitrogen atom but by electrophilic aromatic substitution at C-4 of the phenyl ring to give [(CH3)3Si]2NC6H2('Pr:)SeCl3, which crystallizes as the chloro-bridged dimer in the triclinic system, space group Pi, a - 10.2598(17), b = 13.665(3), c = 9.7838(10) A, a = 90.056(13), ß = 102.439(11), 7 = 70.922(14)°, V = 1262.3(4) A \Z = 1. The dimer contains an essentially planar CUSe^-Cl^SeCU unit, with trans apical (Me3SihNC6H2('Pr)2 groups, resulting in approximately square pyramidal geometry at Se. The bridging Se-Cl distances are unequal at 2.587(2) and 2.749(2) A.en_US
dc.description.peer-reviewYesen_US
dc.identifier.citationMaaninen, A., Boeré, R. T., Chivers, T., & Parvez, M. (1999). Preparation and x-ray structure of 4-N,N'-bis(trimethylsilyl)- amino-3,5-diisopropylphenylselenium trichloride. Zeitschrift für Naturforschung, 54B, 1170-1174.en_US
dc.identifier.urihttps://hdl.handle.net/10133/5349
dc.language.isoen_USen_US
dc.publisherVerlag der Zeitschrift für Naturforschungen_US
dc.publisher.departmentDepartment of Chemistry and Biochemistryen_US
dc.publisher.facultyArts and Scienceen_US
dc.publisher.institutionUniversity of Ouluen_US
dc.publisher.institutionUniversity of Lethbridgeen_US
dc.publisher.institutionUniversity of Calgaryen_US
dc.subjectCrystal structureen_US
dc.subject2,6-diisopropylanilineen_US
dc.subjectAryl selenium trichlorideen_US
dc.subjectBridging chlorideen_US
dc.subjectNMR dataen_US
dc.titlePreparation and x-ray structure of 4-N,N'-bis(trimethylsilyl)- amino-3,5-diisopropylphenylselenium trichlorideen_US
dc.typeArticleen_US
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