Coordination polymers from main group ring compounds

Simple item page
dc.contributor.authorOkeh, Saturday A.
dc.contributor.authorBoeré, René T.
dc.date.accessioned2019-04-29T21:14:17Z
dc.date.available2019-04-29T21:14:17Z
dc.date.issued2016
dc.descriptionSherpa Romeo green journal. Permission to archive accepted author manuscripten_US
dc.description.abstract4,7-dicyano-2,1,3-benzothiadiazole, L1, and diethyl-4,7-dicarboxylato-2,1,3 benzothiadiazole, L2, form coordination polymers with silver(I) salts of weakly-coordinating anions. Synthesis was achieved by the slow diffusion of benzene solutions of the silver salts into dichloromethane solutions of L1 or L2. Slow growth of crystals occurred with partial evaporation of the solvent, leading to a number of different crystalline coordination polymers. For L1, both the nitrile and ring N atoms can coordinate with great variability of structural motifs, whereas for L2 a chelating geometry is always found in which each Ag+ is coordinated by two N and two carbonyl O from different ligands. The resulting coordination polymers form layer structures that tend to fill with solvent benzene molecules in a stoichiometric fashion; the benzenes are found to π-coordinate to silver.en_US
dc.description.peer-reviewYesen_US
dc.identifier.citationOkeh, S. A., & Boeré, R. T. (2016). Coordination polymers from main group ring compounds. Phosphorus, Sulfur and Silicon and the Related Elements, 191I(4), 648-650. doi: 10.1080/10426507.2015.1128927en_US
dc.identifier.urihttps://hdl.handle.net/10133/5346
dc.language.isoen_USen_US
dc.publisherTaylor & Francisen_US
dc.publisher.departmentDepartment of Chemistry and Biochemistryen_US
dc.publisher.facultyArts and Scienceen_US
dc.publisher.institutionUniversity of Lethbridgeen_US
dc.publisher.urlhttps://doi.org/10.1080/10426507.2015.1128927
dc.subject2,1,3-chalcogenadiazolesen_US
dc.subjectSilver(I) saltsen_US
dc.subjectNetwork solidsen_US
dc.subjectSolvent channelsen_US
dc.titleCoordination polymers from main group ring compoundsen_US
dc.typeArticleen_US
Files
Original bundle
Now showing 1 - 2 of 2
Thumbnail Image
Name:
Boeré-coordination-polymers-from-main.pdf
Size:
644.82 KB
Format:
Adobe Portable Document Format
Description:
Download
Thumbnail Image
Name:
Boeré-coordination-polymersVR.pdf
Size:
757.04 KB
Format:
Adobe Portable Document Format
Description:
REQUEST a copy of the final published version
Download
License bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
license.txt
Size:
1.75 KB
Format:
Item-specific license agreed upon to submission
Description:
Download
Collections
Boere, Rene