The solid-state structure of SF4: the final piece of the puzzle

Goettel, James T.; Kostiuk, Nathan; Gerken, Michael

The solid-state structure of SF4: the final piece of the puzzle

dc.contributor.author	Goettel, James T.
dc.contributor.author	Kostiuk, Nathan
dc.contributor.author	Gerken, Michael
dc.date.accessioned	2021-07-15T15:34:56Z
dc.date.available	2021-07-15T15:34:56Z
dc.date.issued	2013
dc.description	Accepted author manuscript	en_US
dc.description.abstract	Solved at last: The crystal structure of solid SF4, which has a melting point of −121 °C, has been obtained. It exhibits weak intermolecular S⋅⋅⋅F interactions. A similar structural motif was observed within a layer of SF4 in [HNC5H3(CH3)2+]2F−⋅⋅⋅SF4[SF5−]⋅3 SF4. The latter structure contains a range of bonding modes between S and F, namely SF5−, F4S⋅⋅⋅F−, F4S⋅⋅⋅FSF4−, and F4S⋅⋅⋅FSF3.	en_US
dc.description.peer-review	Yes	en_US
dc.identifier.citation	Goettel, J. T., Kostiuk, N., & Gerken, M. (2013). The solid-state structure of SF4: The final piece of the puzzle. Angewandte Chemie International Edition, 52(31), 8037-8040. https://doi.org/10.1002/anie.201302917	en_US
dc.identifier.uri	https://hdl.handle.net/10133/5959
dc.language.iso	en_US	en_US
dc.publisher	Wiley	en_US
dc.publisher.department	Department of Chemistry and Biochemistry	en_US
dc.publisher.faculty	Arts and Science	en_US
dc.publisher.institution	University of Lethbridge	en_US
dc.publisher.url	https://doi.org/10.1002/anie.201302917	en_US
dc.subject	Structure elucidation	en_US
dc.subject.lcsh	Crystallography
dc.subject.lcsh	Fluorine
dc.subject.lcsh	Raman spectroscopy
dc.subject.lcsh	Sulfur tetrafluoride
dc.title	The solid-state structure of SF4: the final piece of the puzzle	en_US
dc.type	Article	en_US