X-ray crystal structure of [L2Ag3]+[OTf]−·5C6D6: a monoanionic bisphosphinimine ligand supported trisilver complex
| dc.contributor.author | Drescher, Sam L. | |
| dc.contributor.author | Forfar, Christopher P. | |
| dc.contributor.author | Boeré, René T. | |
| dc.contributor.author | Hayes, Paul G. | |
| dc.date.accessioned | 2022-08-16T19:53:41Z | |
| dc.date.available | 2022-08-16T19:53:41Z | |
| dc.date.issued | 2021 | |
| dc.description | Open access article. Creative Commons Attribution 4.0 International License (CC BY 4.0) applies | en_US |
| dc.description.abstract | The compound bis{μ3-2,5-bis[N-(4-isopropylphenyl)-P,P-diphenylphosphorimidoyl]pyrrol-1-ido-κ3N:N′:N′′}trisilver(I) trifluoromethanesulfonate deuterated benzene pentasolvate, [Ag3(C46H44N3P2)2](CF3O3S)·5C6D6, (I), was synthesized from two equivalents of NaL [L = 2,5-(4-iPrC6H4N=PPh2)C4H2N] and three equivalents of AgOTf (OTf = OSO2CF3). High-quality crystals of (I) formed with five deuterated benzene solvent molecules in the asymmetric unit. Notably, the bond lengths and angles between the three silver atoms are markedly different, unlike in most other reported trisilver complexes that tend to form three equivalent metal centers. Additionally, to the best of our knowledge, this is the first report of a trisilver complex with six nitrogen donors from two bisphosphinimine ligands. | en_US |
| dc.description.peer-review | Yes | en_US |
| dc.identifier.citation | Drescher, S. L., Forfar, C. P., Boeré, R. T., & Hayes, P. G. (2021). X-ray crystal structure of [L2Ag3]+[OTf]−·5C6D6: a monoanionic bisphosphinimine ligand supported trisilver complex. Acta Crystallographica, Section E: Crystallographic Communications, E77(10), 1025-1028. https://doi.org/10.1107/S2056989021009221 | en_US |
| dc.identifier.uri | https://hdl.handle.net/10133/6317 | |
| dc.language.iso | en_US | en_US |
| dc.publisher.department | Department of Chemistry and Biochemistry | en_US |
| dc.publisher.faculty | Arts and Science | en_US |
| dc.publisher.institution | University of Lethbridge | en_US |
| dc.publisher.url | https://doi.org/10.1107/S2056989021009221 | en_US |
| dc.subject | X-ray crystal structure | en_US |
| dc.subject | Phosphinimine | en_US |
| dc.subject | Trisilver | en_US |
| dc.subject | Monoanionic | en_US |
| dc.subject.lcsh | X-ray crystallography | |
| dc.title | X-ray crystal structure of [L2Ag3]+[OTf]−·5C6D6: a monoanionic bisphosphinimine ligand supported trisilver complex | en_US |
| dc.type | Article | en_US |