A rigid anionic Janus bis(NHC) - new opportunities in NHC chemistry

dc.contributor.authorNaz, Nabila R.
dc.contributor.authorSchnakenburg, Gregor
dc.contributor.authorKelemen, Zsolt
dc.contributor.authorGal, Dalma
dc.contributor.authorNyulaszi, Laszlo
dc.contributor.authorBoeré, René T.
dc.contributor.authorStreubel, Rainer
dc.date.accessioned2021-09-22T22:53:52Z
dc.date.available2021-09-22T22:53:52Z
dc.date.issued2021
dc.descriptionOpen access article. Creative Commons Attribution 3.0 Unported License (CC BY 3.0) appliesen_US
dc.description.abstractA phosphanido-type bridged bis(imidazolium) salt, readily prepared in two steps via reductive deselenization of a tricyclic 1,4-diphosphinine diselone, affords access to a novel anionic P-functional tricyclic bis(NHC) via deprotonation. The former also offers a P-functionalization/deprotonation sequence to access the first mixed P-substituted tricyclic bis(NHCs), as well as coordination of the phosphorus centers to rhodium(I) fragments.en_US
dc.description.peer-reviewYesen_US
dc.identifier.citationNaz, N. R., Schnakenburg, G., Kelemen, Z., Gal, D., Nyulaszi, L., Boere, R. T., & Streubel, R. (2021). A rigid anionic Janus bis(NHC) - new opportunities in NHC chemistry. Dalton Transactions, 50(2), 689-695. https://doi.org/10.1039/D0DT03915Ben_US
dc.identifier.urihttps://hdl.handle.net/10133/6037
dc.language.isoen_USen_US
dc.publisherRoyal Society of Chemistryen_US
dc.publisher.departmentDepartment of Chemistry and Biochemistryen_US
dc.publisher.facultyArts and Scienceen_US
dc.publisher.institutionFriedrich-Wilhelms-Universitat Bonnen_US
dc.publisher.institutionBudapest University of Technology and Economicsen_US
dc.publisher.institutionUniversity of Lethbridgeen_US
dc.publisher.urlhttps://doi.org/10.1039/D0DT03915Ben_US
dc.subjectJanus bis(NHC)en_US
dc.subjectNHC chemistryen_US
dc.subjectAnionicen_US
dc.subjectN-heterocyclic carbenesen_US
dc.subjectNHCsen_US
dc.titleA rigid anionic Janus bis(NHC) - new opportunities in NHC chemistryen_US
dc.typeArticleen_US
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