Triamidoamine-supported zirconium: hydrogen activation, Lewis acidity, and rac-lactide polymerization

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dc.contributor.authorLeshinski, Sarah E.
dc.contributor.authorWheaton, Craig A.
dc.contributor.authorSun, Hongsui
dc.contributor.authorRoering, Andrew J.
dc.contributor.authorTanski, Joseph M.
dc.contributor.authorFox, Daniel J.
dc.contributor.authorHayes, Paul G.
dc.contributor.authorWaterman, Rory
dc.date.accessioned2017-10-24T23:34:21Z
dc.date.available2017-10-24T23:34:21Z
dc.date.issued2016
dc.descriptionSherpa Romeo green journalen_US
dc.description.abstractInvestigation of a triamidoamine-supported zirconium hydride intermediate, important to a range of catalytic reactions, revealed the potential Lewis acidity of [k5-N,N,N,N,C-(Me3SiNCH2CH2)2NCH2CH2NSiMe2CH2]Zr (1). A preliminary study of 1 as a precursor for the polymerization of rac-lactide showed modest activity but indicated that five-coordinate zirconium complexes with tetra-N donor ligands may be an avenue for further development in group 4 metal lactide polymerization catalysis.en_US
dc.description.peer-reviewYesen_US
dc.identifier.citationLeshinski, S. E., Wheaton, C. A., Sun, H., Roering, A. J., Tanski, J. M., Fox, D. J., ... Waterman, R. (2016). Triamidoamine-supported zirconium: hydrogen activation, Lewis acidity, and rac-lactide polymerization. RSC Advances, 6, 70581-70585. doi:10.1039/c6ra15617gen_US
dc.identifier.urihttps://hdl.handle.net/10133/4951
dc.language.isoen_USen_US
dc.publisherRoyal Society of Chemistryen_US
dc.publisher.departmentDepartment of Chemistry and Biochemistryen_US
dc.publisher.facultyArts and Scienceen_US
dc.publisher.institutionUniversity of Vermonten_US
dc.publisher.institutionUniversity of Lethbridgeen_US
dc.publisher.institutionVassar Collegeen_US
dc.publisher.institutionBoston Collegeen_US
dc.subjectTriamidoamineen_US
dc.subjectHydrogen activationen_US
dc.subjectLewis acidityen_US
dc.subjectLactide polymerizationen_US
dc.subjectrac-lactideen_US
dc.subject.lcshZirconium
dc.subject.lcshZirconium compounds
dc.subject.lcshLewis acids
dc.subject.lcshCatalysis
dc.subject.lcshActivation (Chemistry)
dc.titleTriamidoamine-supported zirconium: hydrogen activation, Lewis acidity, and rac-lactide polymerizationen_US
dc.typeArticleen_US
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