Fluoride-ion acceptor properties of WSF4: synthesis, characterization, and computational study of the WSF5¯ and W2S2F9¯ anions and 19F NMR spectroscopic characterization of the W2OSF9¯ anion

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dc.contributor.authorNieboer, Jared
dc.contributor.authorHaiges, Ralf
dc.contributor.authorHillary, William
dc.contributor.authorYu, Xin
dc.contributor.authorRichardet, Tyler
dc.contributor.authorMercier, Hélène P. A.
dc.contributor.authorGerken, Michael
dc.date.accessioned2021-08-12T20:37:17Z
dc.date.available2021-08-12T20:37:17Z
dc.date.issued2012
dc.descriptionAuthor accepted manuscripten_US
dc.description.abstractThe new [N(CH3)4][WSF5] salt was synthesized by two preparative methods: (a) by reaction of WSF4 with [N(CH3)4][F] in CH3CN and (b) directly from WF6 using the new sulfide-transfer reagent [N(CH3)4][SSi(CH3)3]. The [N(CH3)4][WSF5] salt was characterized by Raman, IR, and 19F NMR spectroscopy and [N(CH3)4][WSF5]·CH3CN by X-ray crystallography. The reaction of WSF4 with half an aliquot of [N(CH3)4][F] yielded [N(CH3)4][W2S2F9], which was characterized by Raman and 19F NMR spectroscopy and by X-ray crystallography. The WSF5– and W2S2F9– anions were studied by density functional theory calculations. The novel [W2OSF9]− anion was observed by 19F NMR spectroscopy in a CH3CN solution of WOF4 and WSF5–, as well as CH3CN solutions of WSF4 and WOF5–.en_US
dc.description.peer-reviewYesen_US
dc.identifier.citationNieboer, J., Haiges, R., Hillary, W., Yu, X., Richardet, T., Mercier, H. P. A., & Gerken, M. (2012). Fluoride-ion acceptor properties of WSF4: Synthesis, characterization, and computational study of the WSF5¯ and W2S2F9¯ anions and 19F NMR spectroscopic characterization of the W2OSF9¯ anion. Inorganic Chemistry, 51(11), 6350-6359. https://doi.org/10.1021/ic3005882en_US
dc.identifier.urihttps://hdl.handle.net/10133/5997
dc.language.isoen_USen_US
dc.publisherAmerican Chemical Societyen_US
dc.publisher.departmentDepartment of Chemistry and Biochemistryen_US
dc.publisher.facultyArts and Scienceen_US
dc.publisher.institutionUniversity of Lethbridgeen_US
dc.publisher.institutionUniversity of Southern Californiaen_US
dc.publisher.institutionMcMaster Universityen_US
dc.publisher.urlhttps://doi.org/10.1021/ic3005882en_US
dc.subjectSaltsen_US
dc.subjectAnionsen_US
dc.subjectFluorineen_US
dc.subjectNuclear magnetic resonance spectroscopyen_US
dc.subjectMathematical methodsen_US
dc.titleFluoride-ion acceptor properties of WSF4: synthesis, characterization, and computational study of the WSF5¯ and W2S2F9¯ anions and 19F NMR spectroscopic characterization of the W2OSF9¯ anionen_US
dc.typeArticleen_US
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