Electrochemistry of redox-active Group 15/16 heterocycles

Abstract

This review is a critical overview of the literature on electrochemistry of unsaturated ring compounds containing bonds between Group 15 and Group 16 elements (principally S and N), including metallacycles. It contains a detailed compilation of measured redox potentials and the conditions under which these were obtained for over 200 compounds. An introduction to the application of solution electrochemistry to this class of compounds is provided, and the relevance of such measurements to materials design is discussed.