Janus bis(NHCs) tuned by heteroatom-bridge oxidation states
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Royal Society of Chemistry
Abstract
Synthesis of the first tricyclic bis(carbenes) with facially opposed imidazole-2-ylidenes and two linking phosphorus centres in different oxidation states is presented using a modular, high-yield synthetic route. The formation of homo bimetallic coinage metal complexes provides a glimpse on their potential use.
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Open access article. Creative Commons Attribution 3.0 Unported License (CC BY 3.0) applies
Citation
Naz, N. R., Schnakenburg, G., Mikehazi, A., Kelemen, Z., Nyulaszi, L., Boere, R. T., & Streubel, R. (2020). Janus bis(NHCs) tuned by heteroatom-bridge oxidation states. Chemical Communications, 57(17), 2646-2649. https://doi.org/10.1039/C9CC08468A