The structure of the norbornadiene adduct of 5-phenyl-1,3,2,4,6-dithiatriazine
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Date
1986
Authors
Cordes, A. Wallace
Craig, S. L.
Privett, J. A. James
Oakley, Richard T.
Boeré, René T.
Journal Title
Journal ISSN
Volume Title
Publisher
International Union of Crystallography
Abstract
10-Phenyl- 1,8-dithia-9,11,12-triazatetracyclo-
[6.3.1.1 a,6.02,7]tfideca- 1 (11),4,9,8 (12)-tetraene, C ~4-
H13N3S2, Mr-- 287.4, monoclinic, P2 l, a = 5-789 (2),
b=10.064(1), c--11.109(2)A, fl=94.78(2) °, V
= 644.9 (4)/~3, Z = 2, D x = 1.48 g cm -3, 2(Mo Kct)
=0.71073/~, p-- 3.84cm -~, F(000)= 300, T--
293 K, R -- 0.037 for 1203 unique observed reflections.
The norbornadiene bonds to the sulfur atoms in the
exo-fl orientation and the nitrogen atom between the
sulfur atoms is displaced 0.802 (4)/~ from the SNCNS
plane. The C-N bond lengths are equal [1.335 (5)A]
and the S--N bond lengths in a very narrow range of
values [1.637 (4)-1.652 (4) A].
Description
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Keywords
Citation
Cordes, A. W., Craig, S. L., Privett, J. A. J., Oakley, R. T., & Boere, R. T. (1986). The structure of the norbornadiene adduct of 5-phenyl-1,3,2,4,6-dithiatriazine. Acta Crystallographica Section C, Crystal Structure Communications, C42, 508-509.