Show simple item record Goettel, James T. Gerken, Michael 2021-08-04T00:06:29Z 2021-08-04T00:06:29Z 2016
dc.identifier.citation Goettel, J. T., & Gerken, M. (2016). Synthesis and characterization of adducts between SF4 and oxygen bases: Examples of O···S(IV) chalcogen bonding. Inorganic Chemistry, 55(23), 12441-12450. en_US
dc.description Accepted author manuscript en_US
dc.description.abstract Lewis acid–base adducts between SF4 and the oxygen bases tetrahydrofuran, cyclopentanone, and 1,2-dimethoxyethane were synthesized and characterized by Raman spectroscopy and X-ray crystallography. Crystal structures of (SF4·OC4H8)2, SF4·(OC4H8)2, SF4·CH3OC2H4OCH3, and SF4·(O═C5H8)2 show weak S···O chalcogen bonding interactions ranging from 2.662(2) to 2.8692(9) Å. Caffeine, which has three Lewis basic sites, was reacted with SF4 and one aliquot of HF forming C8H10N4O2·2SF4·HF, which was also characterized by X-ray crystallography. Density functional theory calculations aided in the assignment of the vibrational spectra of (SF4·OC4H8)2, SF4·(OC4H8)2, SF4·CH3OC2H4OCH3, and SF4·(O═C5H8)2. Bonding was studied by natural bond order and the quantum theory of atoms in molecules analyses. en_US
dc.language.iso en_US en_US
dc.publisher American Chemical Society en_US
dc.subject Adducts en_US
dc.subject Group 16 compounds en_US
dc.subject.lcsh Oxygen
dc.subject.lcsh Sulfur
dc.subject.lcsh Lewis acids
dc.subject.lcsh Chalcogens
dc.subject.lcsh Molecules
dc.title Synthesis and characterization of adducts between SF4 and oxygen bases: examples of O···S(IV) chalcogen bonding en_US
dc.type Article en_US
dc.publisher.faculty Arts and Science en_US
dc.publisher.department Department of Chemistry and Biochemistry en_US
dc.description.peer-review Yes en_US
dc.publisher.institution University of Lethbridge en_US
dc.publisher.url en_US

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