Browsing Chemistry & Biochemistry by Subject "Fluoride"

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  • Turnbull, Douglas; Gerken, MIchael (Arts and ScienceDepartment of Chemistry and BiochemistryUniversity of Lethbridgehttps://doi.org/10.1107/S2056989020009767, 2020)
    Crystals of 1,10-phenanthrolinium penta­fluorido­oxidotungstate(VI), (1,10-phen-H)[WOF5] (1,10-phen = 1,10-phenanthroline, C12H8N2), were obtained upon hydrolysis of WF6(1,10-phen) in CH3CN at 193 K. The (1,10-phen-H)[WOF5] ...
  • Goettel, James T.; Kostiuk, Nathan; Gerken, MIchael (American Chemical SocietyArts and ScienceDepartment of Chemistry and BiochemistryUniversity of LethbridgeCanadian Centre for Research in Advanced Fluorine Technologieshttps://doi.org/10.1021/acs.inorgchem.6b01112, 2016)
    Adducts between SF4 and a nitrogen base are easily solvolyzed by HF, yielding the protonated nitrogen base and fluoride. Salts resulting from the solvolysis of SF4·NC5H5, SF4·NC5H4(CH3), SF4·NC5H3(CH3)2, and SF4·NC5H4N(CH3)2 ...