Show simple item record Turnbull, Douglas Gerken, MIchael 2021-07-02T16:42:13Z 2021-07-02T16:42:13Z 2020
dc.identifier.citation Turnbull, D., & Gerken, M. (2020). Crystal structure of an ordered [WOF5] ¯ salt: (1,10-phen-H)[WOF5] (1,10-phen = 1,10-phenanthroline. Acta Crystallographica Section E, 76(8), 1345-1348. en_US
dc.description Open access article. Creative Commons Attribution LIcense (CC BY) applies en_US
dc.description.abstract Crystals of 1,10-phenanthrolinium penta­fluorido­oxidotungstate(VI), (1,10-phen-H)[WOF5] (1,10-phen = 1,10-phenanthroline, C12H8N2), were obtained upon hydrolysis of WF6(1,10-phen) in CH3CN at 193 K. The (1,10-phen-H)[WOF5] salt contains a rare example of a [WOF5]− anion in which the oxygen and fluorine atoms are ordered. This ordering was verified by bond-valence determinations and structural comparisons with [Xe2F11][WOF5] and Lewis acid-base adducts of WOF4 with main-group donor ligands. The crystal packing is controlled by N—H⋯F hydrogen bonding that is directed exclusively to the axial F atom as a result of its increased basicity caused by the trans influence of the oxido ligand. en_US
dc.language.iso en_US en_US
dc.subject Tungsten en_US
dc.subject Fluoride en_US
dc.subject Oxide en_US
dc.subject Crystal structure en_US
dc.subject O/F ordered anion en_US
dc.title Crystal structure of an ordered [WOF5]¯ salt: (1,10-phenH) [WOF5] (1,10-phen = 1, 10-phenanthroline en_US
dc.type Article en_US
dc.publisher.faculty Arts and Science en_US
dc.publisher.department Department of Chemistry and Biochemistry en_US
dc.description.peer-review Yes en_US
dc.publisher.institution University of Lethbridge en_US
dc.publisher.url en_US

Files in this item

This item appears in the following Collection(s)

Show simple item record