Hayes, Paul

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Browsing Hayes, Paul by Author "Ojwach, Stephen O."

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    Di­chlorido­bis­­[2-(pyridin-2-yl-κN)-1H-benzimidazole-κN3]nickel(II) monohydrate
    (2020) MacNeil, Connor S.; Ogweno, Aloice O.; Ojwach, Stephen O.; Hayes, Paul
    In the title complex, [NiCl2(C12H9N3)2]·H2O, a divalent nickel atom is coordinated by two 2-(pyridin-2-yl)-1H-benzimidazole ligands in a slightly distorted octa­hedral environment defined by four N donors of two N,N′-chelating ligands, along with two cis-oriented anionic chloride donors. The title complex crystallized with a water mol­ecule disordered over two positions. In the crystal, a combination of O—H⋯Cl, O—H.·O and N—H⋯Cl hydrogen bonds, together with C—H⋯O, C—H⋯Cl and C—H⋯π inter­actions, links the complex mol­ecules and the water mol­ecules to form a supra­molecular three-dimensional framework. The title complex is isostructural with the cobalt(II) dichloride complex reported previously [Das et al. (2011[Das, S., Guha, S., Banerjee, A., Lohar, S., Sahana, A. & Das, D. (2011). Org. Biomol. Chem. 9, 7097-7104.]). Org. Biomol. Chem. 9, 7097–7107].