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dc.contributor.author Okeh, Saturday A.
dc.contributor.author Boeré, René T.
dc.date.accessioned 2019-04-29T21:14:17Z
dc.date.available 2019-04-29T21:14:17Z
dc.date.issued 2016
dc.identifier.citation Okeh, S. A., & Boeré, R. T. (2016). Coordination polymers from main group ring compounds. Phosphorus, Sulfur and Silicon and the Related Elements, 191I(4), 648-650. doi: 10.1080/10426507.2015.1128927 en_US
dc.identifier.uri https://hdl.handle.net/10133/5346
dc.description Sherpa Romeo green journal. Permission to archive accepted author manuscript en_US
dc.description.abstract 4,7-dicyano-2,1,3-benzothiadiazole, L1, and diethyl-4,7-dicarboxylato-2,1,3 benzothiadiazole, L2, form coordination polymers with silver(I) salts of weakly-coordinating anions. Synthesis was achieved by the slow diffusion of benzene solutions of the silver salts into dichloromethane solutions of L1 or L2. Slow growth of crystals occurred with partial evaporation of the solvent, leading to a number of different crystalline coordination polymers. For L1, both the nitrile and ring N atoms can coordinate with great variability of structural motifs, whereas for L2 a chelating geometry is always found in which each Ag+ is coordinated by two N and two carbonyl O from different ligands. The resulting coordination polymers form layer structures that tend to fill with solvent benzene molecules in a stoichiometric fashion; the benzenes are found to π-coordinate to silver. en_US
dc.language.iso en_US en_US
dc.publisher Taylor & Francis en_US
dc.subject 2,1,3-chalcogenadiazoles en_US
dc.subject Silver(I) salts en_US
dc.subject Network solids en_US
dc.subject Solvent channels en_US
dc.title Coordination polymers from main group ring compounds en_US
dc.type Article en_US
dc.publisher.faculty Arts and Science en_US
dc.publisher.department Department of Chemistry and Biochemistry en_US
dc.description.peer-review Yes en_US
dc.publisher.institution University of Lethbridge en_US
dc.publisher.url https://doi.org/10.1080/10426507.2015.1128927


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